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Z-ONA4LIFE: Advancing the Circular Aluminium Foundries Concept

Stage 3

Brine treatment & Recovery of subproducts

The hydrolysis of aluminium salt slag (Stage 1) produces brine with a high sodium (Na) and chlorine (Cl) content. One of the objectives of the Z-ONA4LIFE project is to design a “near-zero” waste process, considering the recovery of by-products from the brine.

The MEDES group at IETcc-CSIC conducted a comprehensive laboratory-scale study to identify the key variables in the process of recovering sodium carbonate (Na2CO3) and calcium chloride (CaCl2). The study assessed the impact of various experimental parameters, such as temperature, time, reagent concentration and pH, on the efficiency of the process and the quality of the resulting products.

Recovery of by-products from brine

Recovery of by-products from brine

This study is particularly relevant because both sodium carbonate and calcium chloride are included in the Best Available Techniques Reference Documents (BREF), which is the European reference for the Large Volume Inorganic Chemicals (LVIC). Sodium carbonate is one of the five “cornerstone” products and calcium chloride is one of the seventeen “representative” products due to their importance to the EU chemical industry and its economic growth.

 

Partner Testimonial

This stage is a significant step towards establishing a comprehensive circular economy strategy for aluminium salt slag that is fully aligned with the Z-ONA4LIFE project's objectives. Recovering by-products reinforces our commitment to a “near-zero waste” production model. This approach maximises resource efficiency and makes a tangible contribution to the environmental and economic sustainability of the aluminium sector. 

Dr. Isabel Padilla
Dr. Isabel Padilla
Tenured scientist, IETcc-CSIC

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